The cooling power of the metal hydride refrigeration system is based on the temperature- and pressure-dependent equilibrium reaction between hydrogen and a metal hydride, which provides ...

Alkene hydroalkylation reactions make alkyl carbon centers by reacting metal hydride species with alkenes. However, controlling the stereochemical selectivity of this reaction has been challenging.

Here, the authors report a Trost-ligand-enabled enantioselective desymmetric beta-hydride elimination reaction from π-allyl-palladium species, providing rapid access to cyclohexenes bearing a ...